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1-
What is Corrosion ? |
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Corrosion which is the
metal's loss of metalic specialities, is a result
of chemical and electrochemical reactions between
the metal and the environment. Most of the metals
are not enduring againist the effects of water and
atmosphere and can easily be corroded under normal
conditions. Except some of the inert metals all
of the metals and their alloys corrode more or less.
Corrosion can be seen in all parts of industry.
Tanks that are in open air, depots, columns, parapets,
vehicles, underground pipe lines, reinforced concrete
irons, port legs, ships, chemical liquid pots in
factories, pipes and many machine parts are faced
with corrosion. All of these constructions become
unserviceable because of corrosion and economical
loss occurs. |
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2-
What is Cathodic Protection ? |
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Cathodic Protection is
making the metal construction which has to be protected,
a catode of a electrochemical cell and stopping
of anodical reactions which occur on the metal surface.
Cathodic Protection 's purpose is the polarization
of potential of the metal to be protected to the
open circuit potential of the anode. To do this,
an impressed current is applied to the metal in the
catodical direction.
There has been great development in Cathodic Protection which began to be applied in 1930s, and has been
the most effective and economical way againist corrosion.
The first application of Cathodic Protection was
in oil pipe lines. Today a lot of metal constructions
like port legs, ships, water and oil storage tanks,
chemical material pots, heat changers, reinforced
concrete irons, etc. are protected catodically.
Especially in order to operate high pressured oil
and natural gas pipe lines safely, Cathodic Protection is necessary.
Cathodic Protection divides into two as impressed current
sourced and sacrificial anoded. a-
Impressed Current Sourced
Cathodic Protection impressed curent sourced Catodic Protection is made
as an outer direct current is applied to the metal.
Direct current (-) end which is supplied from a
transformator redressor system, is tied to the metal
to be protected and the (+) end to a auxiliary anode.
b- Sacrificial Anode Cathodic Protection
In sacrificial anode cathodic protection systems the
metal to be protected is tied with a metal (anode)
which has less negative potential. So a galvanic
cell is formed.by this way metal construction is
made catode. By dissolving galvanic anodes produce
current like a cell. The electrons which occur by
the dissolvement of anode, supply the electrons
which are necessary for catodical reaction by moving
from outer connection to the catode (protected metal
construction). |
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Current capacities
and efficiency of sacrificial anodes are definite.
The surface of the metal construction to be protected
can be kept as cathode by connecting adequate amount
and number of galvanic anodes to the cathodic protection
circuit.
The usage field of Catodic Protection :
Pipe Lines: Fresh water
pipe lines, natural gas pipe lines, waste water
pipes, undersea pipes, fire hidrant pipe lines,
oil pipe lines.
Inner sea constructions and
vehicles: Ships, ferryboats, sea buses, submarine,
yachts, harbour, port, platform, stake legs, float,
etc. |
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Tanks
: Underground LPG and fuel tanks, ground
fuel tanks, waste water tanks, fresh water storage
tanks, etc. |
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Water
systems : Cooling and
heating heat transfer systems, water heating systems,stream
boilers, boiler tanks v.s. |
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3
- What is Sacrificial Anode ? |
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Sacrificial anode which is
used to protect a construction as catodic is an
current producer electrode by dissolving into positive
ion. If
you connect a more active metal like sacrificial anode
to a metal ,which is exposed to corrosion,
the electrons (which is need to catode reaction)
obtains from sacrificial anode's metal automatical
self oxidation reaction. So all of
the anodic reactions on the surface of the protected
metal lasts. Cathodic protection with sacrificial anode
is based on this principle.
To protect a steel pipe line catodically with sacrificial
anodes, a more active metal like magnesium anode
is connected to the pipe line. So in this galvanic
cell, magnesium becomes anode, and the steel pipe
cathode. In the anode by dissolving magnesium makes
out electron. These electrons supply the electron
necessity of catodic reaction. For the system to
work automatically there has to be a potential difference
that is enough to overcome the circuit resistency
between the anode and cathode. |
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4
- What are the types of Sacrificial Anodes ? |
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Ther is three kind of
anodes. Magnesium anode, zinc anode and aluminium
anode . |
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5
- How to make Galvanic Potential Series Inside The
Sea Water ? |
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Galvanic potential values
are given below. If a pair of metals in the list
is connected in sea water the metal above the table
becomes anode and corrodes. |
Galvanic Potential Series Inside The Sea Water ( vs SCE )
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Magnesium |
-1.48
V |
Zinc |
-1.03
V |
Aluminium |
-0.79
V |
Wrought iron and carbon steel |
-0.61
V |
Cast iron |
-0.60
V |
Stainless steel type 430 AISI ( 17 % Cr ) |
-0.57
V |
Stainless steel type 304 AISI (18 % Cr,18 % Ni) |
-0.53
V |
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Rolled brass |
-0.40
V |
Rolled brass (% 80 Copper) |
-0.38
V |
Copper |
-0.36
V |
Aluminium brass
|
-0.32
V |
Nickel |
-0.20
V |
Titanium |
-0.15
V |
Monel |
-0.08
V |
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